Publications 2022


  1. Algarra, M.;  Cuevas, A. L.; Martínez de Yuso, M. V., Romero, R.; Alonso, B.;  Casado, C. M.; Benavente, J. Optical and physicochemical characterizations of a cellulosic/CdSe-QDs@S-DAB5 film. Nanomaterials 2022, 12 (3), 484. DOI: 10.3390/nano12030484.
  2. Almeida-Marrero, V.; Bethlehem, F.; Longo, S.; Candelaria Bertolino, M.; Torres, T.; Huskens, J.; de la Escosura, A. Tailored multivalent targeting of siglecs with photosensitizing liposome nanocarriers. Angewandte Chemie-International Edition 2022. DOI: 10.1002/anie.202206900.
  3. Andrada, D. M.; Sedano, P. S.; Corral, I.; Jana, A.; Danés, S.; Gimferrer, M.; Vos, E.; Yildiz, C. B. The oxidation state in low-valent beryllium and magnesium compounds. Chemical Science 2022. DOI: 10.1039/D2SC01401G.
  4. Barreiro-Lage, D.; Nicolafrancesco, C.; Kocisek, J.; Luna, A.; Kopyra, J.; Alcamí, M.; Huber, B. A.; Martín, F.; Domaracka, A.; Rousseau, P.; Díaz-Tendero, S. Controlling the diversity of ion-induced fragmentation pathways by N-methylation of amino acids. Physical Chemistry Chemical Physics 2022, 24, 941. DOI: 10.1039/D1CP04097A.
  5. Borzęcka, W:; Pereira, P. M. R.; Fernandes, R.; Trindade, T.; Torres, T.; Tomé, J. P. C. Spherical and rod shaped mesoporous silica nanoparticles for cancer-targeted and photosensitizer delivery in photodynamic therapy. Journal of Materials Chemistry B 2022. DOI: 10.1039/D1TB02299G.
  6. Bravo, I.; Prata, M.; Torrinha, A.; Delerue-Matos, C.; Lorenzo, E.; Morais, S. Laccase bioconjugate and multi-walled carbon nanotubes-based biosensor for bisphenol A analysis. Bioelectrochemistry 2022, 144, 108033. DOI: 10.1016/j.bioelechem.2021.108033.
  7. Cárdenas, G.; Lucia-Tamudo, J.; Mateo-de la Fuente, H.; Palmisano, V. F.; Anguita-Ortiz, N.; Ruano, L.; Pérez-Barcia, A.; Díaz-Tendero, S.; Mandado, M.; Nogueira, J. J. MoBioTools: a toolkit to setup QM/MM calculations. ChemRxiv 2022. DOI: 10.26434/chemrxiv-2022-cncp2.
  8. Casellas, N. M.; Dai, G.; Xue, E. Y.; Fonseca, A.; Ng, D. K. P., García-Iglesias, M.; Torres, T. A self-assembled subphthalocyanine-based nanophotosensitiser for photodynamic therapy. Chemical Communications 2022, 58, 669-672. DOI: 10.1039/D1CC05977G.
  9. Casellas, N. M.; Dai, G.; Xue, E. Y.; Vicente-Arana, M. J.; Ng, D. K. P.; Tomás Torres, T.; García-Iglesias, M. Porphyrin-based supramolecular nanofibres as a dynamic and activatable photosensitiser for photodynamic therapy. Biomaterials Science 2022. DOI: 10.1039/D2BM00173J.
  10. Chambers, J. E.; Zubkov, N.; Kubánková, M.; Nixon-Abell, J.; Mela, I.; Abreu, S.; Schwiening, M.; Lavarda, G.; López-Duarte, I.; Dickens, J. A.; Torres, T.; Kaminski, C. F.; Holt, L. J.; Avezov, E.; James A. Huntington, J. A.; St George-Hyslop, P.; Kuimova, M. K.; Marciniak, S. J. Z-α1-antitrypsin polymers impose molecular filtration in the endoplasmic reticulum after undergoing phase transition to a solid state. Science Advances 2022, 8, 14. DOI: 10.1126/sciadv.abm2094.
  11. Chiarinelli, J.; Barreiro-Lage, D.; Bolognesi, P.; Richter, R.; Zettergren, H.; Stockett, M. H.; Díaz-Tendero, S.; Avaldi, L. Electron and ion spectroscopy of the cyclo-alanine-alanine dipeptide. Physical Chemistry Chemical Physics 2022, 24, 5855. DOI: 10.1039/D1CP05811H.
  12. Corpas, J.; Arpa, E. M.; Lapierre, R.; Corral, I.; Mauleón, P., Gómez Arrayás, R., and Juan C. Carretero, J. C. Interplay between the directing group and multifunctional acetate ligand in Pd-catalyzed anti-acetoxylation of unsymmetrical dialkyl-substituted alkynes. ACS Catalysis 2022, 12, XXX, 6596-6605. DOI: 10.1021/acscatal.2c00710.
  13. Cristobal, C.; Gaviña, D.; Alonso, I.; Ribagorda, M.; Carlos Carretero, J. C.; del Pozo Losada, C.; Adrio, J. Catalytic enantioselective intramolecular 1,3-dipolar cycloaddition of azomethine ylides with fluorinated dipolarophiles. Chemical Communications 2022. DOI: 10.1039/D2CC02902B.
  14. del Río-Rodríguez, R.; Fragoso-Jarillo, L.; Garrido-Castro, A. F.; Maestro, M. C.; Fernández-Salas, J. A.; Alemán, J. General electrochemical Minisci alkylation of N-heteroarenes with alkyl halides. Chemical Science 2022. DOI: 10.1039/D2SC01799G.
  15. del Río-Rodríguez, R.; Westwood, M. T.; Sicignano, M.; Juhl, M.; Fernández-Salas, J. A.; Alemán J.; Smith A.D. Isothiourea-catalysed enantioselective radical conjugate addition under batch and flow conditions. ChemComm 2022. DOI: 10.1039/D2CC02432B.
  16. Ganguly, S.; Barreiro-Lage, D.; Walsh, N.; Sorensen, S. L.; Díaz-Tendero, S.; Gisselbrecht, M. The origin of enhanced O2+ production from photoionized CO2 clusters. Communications Chemistry 2022, 5, 16. DOI: 10.1038/s42004-022-00629-z.
  17. García-Arroyo, P., Martínez-Periñán, E., Cabrera-Trujillo, J.J.; Salagre, E.; G. Michel, E.; Martínez, J. I.; Lorenzo, E.; Segura, J. L. Pyrenetetraone-based covalent organic framework as an effective electrocatalyst for oxygen reduction reaction. Nano Research 2022. DOI: 10.1007/s12274-021-4043-2.
  18. Guerra, C.; Kumar, S.; Aguilar-Galindo, F.; Díaz-Tendero, S.; Lozano, A. I.; Mendes, M.; Oller, J. C.; Limao-Vieira, P.; García, G. Total electron detachment and induced cationic fragmentation cross sections for superoxide anion (O2) collisions with benzene (C6H6) molecules. International Journal of Molecular Sciences 2022, 23, 1266. DOI: 10.3390/ijms23031266.
  19. Guerrero-Corella, A.; Fraile, A.; Alemán, J. Intramolecular hydrogen-bond activation: Strategies, benefits, and influence in catalysis. ACS Org. Inorg. Au 2022, DOI: 10.1021/acsorginorgau.1c00053.
  20. Guisán-Ceinos, S.; Rivero, A. R.; Romeo-Gella, F.; Simón-Fuente, S.; Gómez-Pastor, S.; Natalia Calvo, N.; Orrego, A. H.; Guisán, J. M.; Corral, I.; Sanz-Rodriguez, F.; Ribagorda, M. Turn-on fluorescent biosensors for imaging hypoxia-like conditions in living cells. Journal of the American Chemical Society 2022. DOI: 10.1021/jacs.2c01197.
  21. Gutiérrez-Gálvez, L.; del Caño, R.; Menéndez-Luque, I.; García-Nieto, D.; Rodríguez-Pena, M.; Luna, M.; Pineda, T.; Pariente, F.; García-Mendiola, T.; Lorenzo, E. Encarnación Lorenzo, E. Electrochemiluminescent nanostructured DNA biosensor for SARS-CoV-2 detection. Talanta 2022, 240, 123203. DOI: 10.1016/j.talanta.2021.123203.
  22. Gutiérrez-Sánchez, C.; Lorenzo, E. Advances on oxidase enzymes modified nanoporous carbon and gold surfaces for bioelectrochemical applications. Journal of the Electrochemical Society 2022, 169, 027513 DOI: 10.1149/1945-7111/ac527b.
  23. Jiménez-Almarza, A.; López-Magano, A.; Mas-Ballesté, R.; Alemán, J. Tuning the activity−stability balance of photocatalytic organic materials for oxidative coupling reactions. ACS Applied Materials Interfaces 2022. DOI: 10.1021/acsami.2c01646
  24. Lamsabhi, A. M.; Montero-Campillo, M.M.; Mó, O.; Yáñez, M. A theoretical survey of the UV-visible spectra of axial and peripheral substituted boron subphthalocyanines. Computation 2022, 10 (2), 14. DOI: 10.3390/computation10020014.
  25. Manjón-Mata, I.; Teresa Quirós, M.; Velasco-Juárez, E.; Buñuel, E.; Cárdenas, D. J. Nickel-catalyzed hydroborylative polycyclization of allenynes: an atom-economical and diastereoselective synthesis of bicyclic 5-5 fused rings. Adv. Syth. Catal. 2022. DOI: adsc.202101462.
  26. Martín-Illán, J. A.; Suárez, J. A.; Gómez-Herrero, J.; Ares, P.; Gallego-Fuente, D.; Cheng, Y.; Dan Zhao,Daniel Maspoch,Félix Zamora, F. Ultralarge free-standing imine-based covalent organic framework membranes fabricated via compression. Advanced Science 2022, 9 (7), 2104643. DOI: 10.1002/advs.202104643.
  27. Martínez-Fernández, M.; Gavara, R.; Royuela, S.; Fernández-Ecija, L.; Martínez, J. I.; Zamora, F.; Segura, J. L. Following the light: 3D-printed COF@poly(2-hydroxyethyl methacrylate) dual emissive composite with response to polarity and acidity. Journal of Materials Chemistry A, 2022, 10, 4634-4643. DOI: 10.1039/D1TA09614A.
  28. Martínez-Fernández, M.; Martínez-Periñán, E.; Royuela, S.; José I.Martínez, J. I.; Zamora, F.; Lorenzo, E.; Segura, J. L. Covalent organic frameworks based on electroactive naphthalenediimide as active electrocatalysts toward oxygen reduction reaction. Applied Materials Today 2022, 26, 101384. DOI: 10.1016/j.apmt.2022.101384
  29. Martínez-Periñán, E.; Martínez-Sobrino, A.; Bravo, I.; García-Mendiola, T.; Mateo-Martí, E.; Pariente, F.; Lorenzo, E. Neutral red-carbon nanodots for selective fluorescent DNA sensing. Analytical and Bioanalytical Chemistry 2022. DOI:
  30. Mishra, D.; Reino-González, J.; Obaid, R.; LaForge, A. C.; Díaz-Tendero, S.; Martín, F.; Berrah, N. Ultrafast molecular dynamics in ionized 1- and 2-propanol: From simple fragmentation to complex isomerization and roaming mechanisms. Physical Chemistry Chemical Physics 2022, 24, 433. DOI: 10.1039/D1CP04011A.
  31. Mollari, L.; Valle-Amores, M. A.; Martínez-Gualda, A. M.; Marzo, L.; Fraile, A.; Aleman, J. Asymmetric synthesis of cyclic beta-amino carbonyl derivatives by a formal [3 + 2] photocycloaddition. Chemical Communications 2022, 58, 1334-1337. DOI: 10.1039/D1CC05867C
  32. Montero-Campillo, M. M.; Mó, O.; Yáñez, M. Malonaldehyde-like systems: BeF2 clusters. A subtle balance between hydrogen bonds, beryllium bonds and resonance. Sci 2022, 4 (1), 7. DOI: 10.3390/sci4010007.
  33. Nova-Fernández, J. L.; García, M. J.; Mollari, L.; Pascual-Coca, G.; Cabrera, S.; Alemán, J. Continuous-flow synthesis of alkyl zinc sulfinates for the direct photofunctionalization of heterocycles ChemComm 2022. DOI: Accepted manuscript.
  34. Nowok, A.; Cieslik, W; Grelska, J.; Jurkiewicz, K.; Makieieva, N.; Kupka, T.; Alemán, J.; Musioł, R; Pawlus, S. Simple rules for complex near-glass-transition phenomena in medium-sized Schiff bases. International Journal of Molecular Sciences 2022, 23 (9), 5185. DOI: 10.3390/ijms23095185.
  35. Platzer, B.; Berionni Berna, B.; Bischetti, M.; Cicero, D. O.; Paolesse, R.; Nardis, S.; Torres, T.; Guldi, D. M. Exploring the association of electron-donating corroles with phthalocyanines as electron acceptors. Chemistry – A European Journal 2022. DOI: 10.1002/chem.202103891.
  36. Rey-Tarrío, F.; Guisán-Ceinos, S.; Cuerva, J. M.; Miguel, D.; Ribagorda, M.; Quiñoá, E.; Freire, F. Photostability and dynamic helical behavior in chiral poly(phenylacetylene)s with a preferred screw-sense. Angewandte Chemie-International Edition 2022. DOI: 10.1002/anie.202207623.
  37. Romero-Muñiz, I.; Romero-Muñiz, C.; del Castillo-Velilla, I.; Marini, C.; Calero, S.; Zamora, F.; Platero-Prats, A.E. Revisiting vibrational spectroscopy to tackle the chemistry of Zr6O8 metal-organic framework nodes. ACS Applied Materials & Interfaces 2022. DOI: 10.1021/acsami.2c04712.
  38. Rodríguez, R.; Sicignano, M.; Alemán, J. Fluorinated sulfinates as source of alkyl radicals in the photo‐enantiocontrolled β‐functionalization of enals. Angewandte Chemie International Edition 2022, e202112632. DOI: 10.1002/anie.202112632.
  39. Salaverri, N.; Carli, B; Díaz-Tendero, S.; Marzo, L.; Alemán, J. Enantioselective addition of remote alkyl radicals to double bonds by photocatalytic proton-coupled electron transfer (PCET) deconstruction of unstrained cycloalkanols. Organic Letters 2022, 24 (17) 3123-3127. DOI: 10.1021/acs.orglett.2c00662.
  40. Salaverri, N.; Carli, B.; Gratal, P.; Marzo, L.; Alemán, J. Remote Giese radical addition by photocatalytic ring opening of activated cycloalkanols. Advanced Synthesis and Catalysis 2022. DOI: 10.1002/adsc.202200220.
  41. Serrano-Molina, D.; Montoro-García, C.; Mayoral, M. J.; de Juan, A.; González-Rodríguez, D. Self-sorting governed by chelate cooperativity. Journal of the American Chemical Society 2022. DOI: 10.1021/jacs.1c13295.
  42. Sun, Q.; Mateo, L. M.; Robles, R.; Ruffieux, P., Bottari, G.; Torres, T.; Fasel, R.; Lorente, N. Magnetic interplay between π-electrons of open-shell porphyrins and d-electrons of their central transition metal ions. Advanced Science 2022. DOI: 10.1002/advs.202105906.
  43. Torres, I.; Villa-Manso, A. M.; Revenga-Parra, M.; Gutiérrez-Sánchez, C.; Aldave, D. A.; Salagre, E.; García Michel, E.; Varela, M.;  Gómez-Herrero, J.; Lorenzo, E.; Pariente, F.; Zamora, F. Preparation of high-quality few-layers bismuthene hexagons. Applied Materials Today 2022, 101360. DOI: 10.1016/j.apmt.2021.101360.
  44. Valle-Amores, M. A.; Blanco, M.; Agnoli, S.; Fraile, A.; Alemán, J. Oxidized multiwalled nanotubes as efficient carbocatalyst for the general synthesis of azines. Journal of Catalysis 2022, 406, 174. DOI: 10.1016/j.jcat.2022.01.009.
  45. Xavier, J. A. M.; Viñas, C.; Lorenzo, E.; García-Mendiola, T.;  Francesc Teixidor, F. Potential application of metallacarboranes as internal reference: An electrochemical comparative study to ferrocene. Chemical Communications 2022, 58, 4196-4199. DOI:
  46. Yáñez, M.; Ortíz-Chi, F.; Merino, G.; Alkorta, I. Dismantlement of ammonia upon interaction with Ben (n ≤ 10) clusters. Journal of Computational Chemistry 2022. DOI 10.1002/jcc.26843.
  47. Xiong, Y.; Tian, T.; L’Hermitte, A.; Méndez, A. S. J.; Danaci, D.; Platero-Prats, A. E.; Petit, C. Using silver exchange to achieve high uptake and selectivity for propylene/propane separation in zeolite Y. Chemical Engineering Journal 2022 446, 137104. DOI: 10.1016/j.cej.2022.137104.
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